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PERIODIC TABLE
Modern Periodic table
Modern Periodic Law :
The recent work has established that the
fundamental property of an atom is atomic number and not atomic weight.
Therefore, atomic number is taken as the basis of the classification of the
elements. The modern periodic law was given by Moseley, it may be stated as :
''The properties of elements are periodic functions of their atomic number".
Modern periodic table is also called long form of the periodic table
or Bohr’s table. In this table, the elements are arranged in order of their
increasing atomic number. It consists of 4 blocks (s, p, d and f), 18 groups
numbered from 1 to 18 and 7 periods numbered from 1 to 7.
Short tricks to learn periodic table
Blocks :
The periodic table is divided into four main blocks (s, p, d
and f) depending upon the subshell to which the valence electron enters
into.
(1) Elements of group 1 and 2 constitute s-Block.
(2) Elements of group 13, 14, 15, 16, 17, 18 constitute p-Block.
(3) Elements of group 3, 4, 5, 6, 7, 8, 9, 10, 11, 12 constitute d-Block.
(4) The f-Block elements comprise two horizontal rows placed at the
bottom of the periodic table to avoid its unnecessary expansion.
Elements of s- and p-blocks are called normal or representative
elements, those of d-block are called transition elements while the f-block
elements are called inner transition elements.
Periods :
The horizontal rows are called periods. There are seven periods
in the long form of the periodic table,
(1) Ist period ( H ⟶ He) contains 2 elements. It is the shortest
period.
(2) 2nd period ( Li ⟶ Ne) and 3rd period
( Na ⟶ Ar) contains 8 elements each. These are short periods.
(3) 4th period
( K⟶ Kr) and 5th period
( Rb ⟶ Xe) contains 18 elements each. These are long periods.
(4) 6th period
( Cs ⟶ Ra )consists of 32 elements and is the
longest period.
(5) 7th period starting with
Fr is incomplete and consists of 19
elements.
Groups:
The 18 vertical columns are called groups. The elements belonging to a particular group is known as a family and is usually named after the first number. Apart from this some of the groups are given typical names as examplified beneath,
(1) Elements of group 1 are called Alkali-Metals.
(2) Elements of group 2 are called Alkaline Earths.
(3) Elements of group 3 are called Pnicogens.
(4) Elements of group 16 are called Chalcogens.
(5) Elements of group 17 are called Halogens.
(6) Elements of group 18 are called Noble Gases or Aerogens.
All the other groups are named after the first member of each group.
NOMENCLATURE OF ELEMENTS WITH
ATOMIC NUMBERS > 100
The naming of the new elements had been
traditionally the privilege of the discoverer (or
discoverers) and the suggested name was
ratified by the IUPAC. In recent years this has
led to some controversy. The new elements with
very high atomic numbers are so unstable that
only minute quantities, sometimes only a few
atoms of them are obtained. Their synthesis
and characterisation, therefore, require highly sophisticated costly equipment and laboratory.
Such work is carried out with competitive spirit
only in some laboratories in the world.
Scientists, before collecting the reliable data on
the new element, at times get tempted to claim
for its discovery. For example, both American
and Soviet scientists claimed credit for
discovering element 104. The Americans
named it Rutherfordium whereas Soviets
named it Kurchatovium. To avoid such
problems, the IUPAC has made
recommendation that until a new element’s
discovery is proved, and its name is officially
recognised, a systematic nomenclature be
derived directly from the atomic number of the
element using the numerical roots for 0 and
numbers 1-9.These are shown in Table
The roots are put together in order of digitswhich make up the atomic number and “ium”
is added at the end. The IUPAC names for
elements with Z above 100 are shown in
Table
COMPOUNDS OF ALKALI METALS 1. Sodium (Na) , Natrium Extraction of sodium : Down's Process By Electrolysis of fused NaCl + CaCl 2 + NaF At cathode (Iron Vessel) : Na+ +e– ⟶ Na(s) At Anode (Graphite) : 2Cl– → Cl 2 + 2e– (i) (CaCl 2 + NaF) is used to lower Melting point (8000 C) of NaCl to about 6000 C. (ii) Aqueous sodium chloride cannot be used for preparing sodium by electrolysis. Because instead of metallic sodium, hydrogen gas will be liberated at cathode. Properties sodium , Natrium (i) sodium is a crystalline soft metal. (ii) Highly reactive, so kept in kerosene. (iii) Na dissolves in liquid NH3 to give blue solution. Uses of sodium , natrium (i) In the preparation of sodium amalgam (used as reducing agent) (ii) In sodium vapour lamp, which emits monochromatic yellow light. (iii) As heat transfer medium in nuclear reactors. 2. Sodium chloride NaCl Occ...
Chemistry 101: A Beginner's Guide to Understanding the World Around Us Chemistry What is Chemistry ? Chemistry is the study of matter and its properties, composition, and interactions with other substances. It is a fundamental science that encompasses a wide range of topics, from the behavior of atoms and molecules to the reactions that occur in living organisms. Chemistry is the foundation of modern technology and plays a critical role in fields such as medicine, engineering, and materials science. At its core, chemistry is concerned with understanding the structure and behavior of matter at the atomic and molecular level. Chemists study the properties of elements, the structure of molecules, and the forces that govern chemical reactions. They also investigate the behavior of matter under different conditions, such as temperature, pressure, and concentration. One of the key aspects of chemistry is the concept of the chemical bond, which is the force that holds atoms together in m...
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